Objective: This study aimed to develop a green and environment-friendly sodium alginate/starch/tea powder composite membrane. Methods: Tea polysaccharides with different mass fractions were added to the sodium alginate/starch/tea powder composite film to investigate the influence of tea polysaccharides on the properties of sodium alginate/starch/tea powder composite film. Therefore, full infrared barrier, color difference, water solubility, water vapor permeability, tensile strength, elongation at break, thickness, water content, free radical clearance and bacteriostasis were measured. Results: A strong interaction between tea polysaccharides and sodium alginate were found. The composite film with tea polysaccharide content of 5% exhibited the best comprehensive performance. The best bacteriostatic performance was observed when the tensile strength, elongation at break, water vapor permeability were 9.71 MPa, 25.42%, and 2.38×10^-9 g瘙簚mm/(cm²瘙簚d瘙簚Pa), respectively. The antioxidant activity of the composite membrane increased with the increase of the amount of tea polysaccharide added, with a maximum of 85.49%. Conclusion: Tea polysaccharides can improve physicochemical properties, antibacterial and antioxidant properties of the composite membrane. When the mass fraction of tea polysaccharides was 5.00%, the composite membrane had the best mechanical, moisture, and antibacterial properties.