An analytical method for the simultaneous determination of 19 kinds of organochlorine pesticides in apple-pear was established based on optimized solid-phase extraction coupled with gas chromatography-mass spectrometry（SPE-GC/MS）. Different extraction conditions, included extraction solvent, extraction solvent volume, sample weight, solid phase extraction clean-up and eluent were optimized during the sample pretreatment. The quantification were analyzed by GC/MS in selected ion monitoring （SIM） mode and the external standard method. The method showed good linearity (R²≥0.996 7) for all the pesticides. The recoveries at three spiked levels (20, 40, and 200 μg/kg) ranged from 86.1% to 108.9% with the relative standard deviation below 10%. The limit of detection ranged from 3 to 6 μg/kg and the limit of quantification ranged from 10.0 to 20.0 μg/kg the for 19 kinds of pesticides, respectively. The method was simple, accurate and showed high sensitivity for screening and detection of the 19 kinds of pesticides in apple-pear.