油茶果壳纤维素纳米晶制备及其对茶油Pickering乳液稳定性的影响
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1长沙理工大学食品与生物工程学院,湖南 长沙 410114;2湖南省林业科学院木本油料资源利用 全国重点实验室,湖南 长沙 410004

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肖志红(1974—),男,湖南省林业科学院研究员,博士。E-mail: xzhh1015@163.com
王建辉(1980—),男,长沙理工大学教授,博士。E-mail: wangjh0909@163.com

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长沙市自然科学基金(编号:kq2402137);长沙现代食品创新研究院科研项目(编号:2023ZSJYF001);国家重点研发计划“可再生能源技术”重点专项(编号:2024YFB4205901)


Preparation of cellulose nanocrystals from the shells of Camellia oleifera Abel and their effect on the stability of camellia oil Pickering emulsions
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1School of Food Science and Bioengineering, Changsha University of Science and Technology, Changsha, Hunan 410114, China;2State Key Laboratory of Woody Oil Resources Utilization, Hunan Academy of Forestry, Changsha, Hunan 410004, China

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    摘要:

    目的 制备油茶果壳纤维素纳米晶(SCOA-CNCs),用于稳定茶油Pickering乳液,探究茶油Pickering乳液贮藏稳定性和环境稳定性。方法 通过漂白和碱处理提取油茶果壳纤维素,采用硫酸水解法制备SCOA-CNCs,利用扫描电子显微镜、傅里叶变换红外光谱和X射线衍射等技术进行表征。将SCOA-CNCs用于稳定茶油Pickering乳液,考察油水比和颗粒浓度对乳液的影响,并评估乳液在不同环境下的稳定性。结果 制备出棒状SCOA-CNCs,平均长度(191.4±15.9) nm,直径(19.4±1.4) nm,结晶度达73.46%。油水比3∶7 (mL/mL)或颗粒质量浓度10 mg/mL时,能够形成液滴均一、稳定性优异的茶油Pickering乳液。SCOA-CNCs稳定的茶油Pickering乳液在广泛的温度(20~100 ℃)、pH(3~11)和离子强度(≤500 mmol/L)范围内均未发生破乳现象。结论 油茶果壳纤维素纳米晶稳定的茶油Pickering乳液表现出优异的贮藏稳定性和环境稳定性。

    Abstract:

    Objective To prepare cellulose nanocrystals from the shells of Camellia oleifera Abel (SCOA-CNCs) for stabilizing camellia oil Pickering emulsions, and to investigate the storage stability and environmental stability of the resulting emulsions.Methods Cellulose is extracted from SCOA through bleaching and alkali treatment, and SCOA-CNCs are prepared by sulfuric acid hydrolysis and characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The SCOA-CNCs are employed to stabilize camellia oil Pickering emulsions, the effects of the oil-to-water ratio and particle concentration on the emulsions are examined, and the stability of the emulsions under different environmental conditions is evaluated.Results Rod-shaped SCOA-CNCs are successfully prepared, with an average length of (191.4±15.9) nm, an average diameter of (19.4±1.4) nm, and a crystallinity index of 73.46%. When the oil-to-water ratio is lower than 3∶7 (mL/mL) or the particle mass concentration exceeds 10 mg/mL, camellia oil Pickering emulsions with uniform droplet size and excellent stability are formed. The camellia oil Pickering emulsions stabilized by SCOA-CNCs exhibit no demulsification over a wide range of temperatures (20~100 ℃), pH(3~11), and ionic strengths (≤500 mmol/L).Conclusion Camellia oil Pickering emulsions stabilized by SCOA-CNCs demonstrate excellent storage stability and environmental stability.

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金晟,谢淑婷,肖志红,等.油茶果壳纤维素纳米晶制备及其对茶油Pickering乳液稳定性的影响[J].食品与机械,2026,42(6):91-100.
JIN Sheng, XIE Shuting, XIAO Zhihong, et al. Preparation of cellulose nanocrystals from the shells of Camellia oleifera Abel and their effect on the stability of camellia oil Pickering emulsions[J]. Food & Machinery,2026,42(6):91-100.

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  • 收稿日期:2026-02-16
  • 最后修改日期:2026-04-30
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  • 在线发布日期: 2026-07-13
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