Arrow-SPME-GC-MS结合化学计量法比较焙烤和微波核桃油中气味化合物的差异
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濮阳医学高等专科学校,河南 濮阳 457000

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许晓雪(1991—),女,濮阳医学高等专科学校讲师,硕士。E-mail:xuxiaoxue2233@163.com

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河南省高等学校重点科研项目(编号:23B350006)


Differences in odor compounds between roasted and microwaved walnut oils compared by Arrow-SPME-GC-MS combined with stoichiometry method
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Puyang Medical College, Puyang, Henan 457000, China

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    摘要:

    目的 比较焙烤和微波条件对核桃油中气味化合物的影响。方法 采用气相色谱—质谱分析(GC-MS)对焙烤核桃油(140 ℃焙烤15,30 min;160 ℃焙烤15,30 min)和微波核桃油(700 W处理1,3,5,7 min)中气味化合物进行鉴定。结果 共鉴定出74种气味化合物,且随着焙烤温度的增高以及微波时间的延长,气味化合物的质量分数逐渐增加。醛类和杂环类是核桃油中最主要的气味化合物。焙烤核桃油(160 ℃ 烘焙30 min)和微波核桃油(700 W处理7 min)中的关键气味化合物为3-甲基丁醛、戊醛、苯乙醛、2,3-丁二酮、2,3-戊二酮、2-戊基呋喃和2-乙基-6-甲基吡嗪。焙烤核桃油(160 ℃烘焙15~30 min)和微波核桃油(720 W处理7 min)的焙烤气味最强;其次是焙烤核桃油(140 ℃烘焙30 min)和微波核桃油(720 W处理3~5 min);而焙烤核桃油(140 ℃烘焙15 min)和微波核桃油(720 W处理1 min)的焙烤气味最弱。结论 焙烤通过高温长时间加热(160 ℃焙烤30 min)更有利于杂环类化合物的生成,而微波处理在较短时间内(7 min)即可达到与高温焙烤相当的风味强度,均可有效提升核桃油的风味强度。

    Abstract:

    Objective To compare the effects of roasting and microwave conditions on odor compounds in walnut oil.Methods Identification of odor compounds in roasted walnut oil (140 ℃ roasting for 15 and 30 min; 160 ℃ roasting for 15 and 30 min) and microwaved walnut oil (700 W for 1, 3, 5, and 7 min) is performed by gas chromatography-mass spectrometry (GC-MS).Results A total of 74 odor compounds are identified, and the mass fraction of odor compounds gradually rises with increasing roasting temperature and microwave time. Aldehydes and heterocycles are the most dominant odor compounds in walnut oil. The 3-methyl butanal, pentanal, phenylacetaldehyde, 2,3-butanedione, 2,3-pentanedione, 2-pentylfuran, and 2-ethyl-6-methylpyrazine are determined to be the key odor compounds in roasted walnut oil (160 ℃ roasting for 30 min) and microwaveable walnut oil (700 W for 7 min). The roasted walnut oil (160 ℃ roasting for 15~30 min) and microwave walnut oil (720 W for 7 min) have the strongest odor, followed by roasted walnut oil (140 ℃ roasting for 30 min) and microwave walnut oil (720 W for 3~5 min); While roasted walnut oil (140 ℃ roasting for 15 min) and microwave walnut oil (720 W for 1 min) have the weakest odor.Conclusion Roasting at high temperature for a long time (160 ℃ roasting for 30 min) promotes the formation of heterocyclic compounds more effectively, while microwave treatment can achieve a comparable flavor intensity in a shorter time (7 min). Both methods are effective in enhancing the odor intensity of walnut oil.

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许晓雪. Arrow-SPME-GC-MS结合化学计量法比较焙烤和微波核桃油中气味化合物的差异[J].食品与机械,2025,41(4):27-36.
XU Xiaoxue. Differences in odor compounds between roasted and microwaved walnut oils compared by Arrow-SPME-GC-MS combined with stoichiometry method[J]. Food & Machinery,2025,41(4):27-36.

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  • 收稿日期:2024-09-05
  • 最后修改日期:2025-03-11
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  • 在线发布日期: 2025-06-02
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