鼠尾草酸中多环芳烃去除工艺及抗氧化特性
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(晨光生物科技集团股份有限公司 ,河北 邯郸 057250)

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袁瑞(1987—),女,晨光生物科技集团股份有限公司工程师。E-mail:yuanrui890219@163.com

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河北省省级科技计划资助(编号:22567690H)


Process for removing polycyclic aomatic hydrocarbons from carnosic acid and its antioxidant
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(Chenguang Biotech Group Co ., Ltd., Handan , Hebei 057250 , China)

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    摘要:

    [目的]提高鼠尾草酸生产过程中 4种典型多环芳烃的管控效率。[方法]以鼠尾草酸收率和多环芳烃残留量为评价指标,考察活性炭添加量、萃取温度、活性炭在系统中运行时间对多环芳烃残留量和鼠尾草酸收率的影响。向油脂中添加抗氧化剂并进行高温加速氧化试验,测定过氧化值指标评价抗氧化特性。[结果]使用活性炭脱除鼠尾草酸中多环芳烃的最佳工艺为活性炭添加量 0.3%,萃取温度 50 ℃,运行时间 10 min,此条件下鼠尾草酸收率为 94.85%,多环芳烃残留量为 43.12 μg/kg。贮藏 30 d内,同一质量浓度下,4种抗氧化剂的抗氧化效果为叔丁基对苯二酚 (TBHQ)>鼠尾草酸 >丁基羟基茴香醚 (BHA)>VE。[结论]使用活性炭对鼠尾草酸进行多环芳烃去除工艺可行,在确定的条件下可以获得较高的鼠尾草酸收率。从长远来看,0.02%鼠尾草酸的抗氧化效果与 0.02% TBHQ 的相当。

    Abstract:

    [Objective] To investigate the optimal technical conditions for the removal of polycyclic aromatic hydrocarbons (PAHs ) in carnosic acid production.[Methods] With carnosic acid yield and PAHs residue as evaluation indexes,single factor test and orthogonal test were used to study the effects of activated carbon addition,extraction temperature and activated carbon operation time in the system on PAHs residue and carnosic acid yield.Antioxidants were added to oil and high temperature accelerated oxidation test was carried out,then the peroxide value index was measured to evaluate the anti -oxidation properties.[Results]] The optimal process for removing PAHs from carnosic acid with activated carbon was found that its addition ratio was 0.3%,extraction temperature was at 50 ℃ and operation time was 10 minutes.Under these conditions,a carnosic acid yield of 94.85% was achieved with residual PAHs at 43.12 μg/kg extraction storage period and at the same concentration,the anti -oxidation effects of the four antioxidants were TBHQ >carnosic acid >BHA >VE.[Conclusion] It is feasible to remove PAHs from carnosic acid with using activated carbon while achieving a high yield of carnosic acid (CA) under specific conditions.In the long term,the anti -oxidation effect of 0.02% carnosic acid is equivalent to that of 0.02% TBHQ and the use of natural antioxidants is beneficial to human health.

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赵益菲,袁 瑞,尚红岩,等.鼠尾草酸中多环芳烃去除工艺及抗氧化特性[J].食品与机械,2024,40(11):187-193.
ZHAO Yifei, YUAN Rui, SHANG Hongyan, et al. Process for removing polycyclic aomatic hydrocarbons from carnosic acid and its antioxidant[J]. Food & Machinery,2024,40(11):187-193.

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  • 收稿日期:2024-04-02
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  • 在线发布日期: 2025-02-18
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