纳米碳酸钙表面改性沸石对模拟蔗汁中酚酸的吸附性能
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(广西科技师范学院食品与生化工程学院,广西 来宾 546119)

作者简介:

柳富杰,男,广西科技师范学院讲师,硕士。

通讯作者:

潘莉莉(1987—),女,广西科技师范学院工程师,硕士。E-mail:pll0309@163.com

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广西自然科学青年科学基金项目(编号:2022GXNSFBA035617);广西糖资源工程技术研究中心(编号:桂科AD16450040);广西高校制糖工程综合技术重点实验室(编号:桂教科研[2016]6号)


Study on the adsorption properties of nano-calcium carbonate surface modified zeolite to phenolic acid in simulated cane juice
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(College of Food and Biochemical Engineering, Guangxi Science and Technology Normal University, Laibin, Guangxi 546119, China)

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    摘要:

    目的:探讨纳米碳酸钙改性沸石(CaCO3@ZL)对模拟蔗汁中酚酸的吸附性能及其机理。方法:以沸石(ZL)为支撑骨架,通过共沉淀法在沸石表面负载纳米碳酸钙制备纳米碳酸钙改性沸石(CaCO3@ZL)并用于模拟蔗汁中酚酸的吸附。利用X-衍射(XRD)和红外光谱(FTIR)对改性前后的沸石进行表征,通过静态吸附试验和动力学模型拟合研究CaCO3@ZL对酚酸的吸附特性。结果:改性过程成功地在沸石表面负载纳米碳酸钙制备出CaCO3@ZL。CaCO3@ZL相对于未改性的ZL对酚酸的吸附量提高了40.34%,在600 min达到吸附平衡;CaCO3@ZL对酚酸的吸附过程符合Freundlich等温吸附模型和准二级吸附动力学模型,经过5次再生后CaCO3@ZL对酚酸仍可以保持初次吸附量的80.39%。结论:CaCO3@ZL对模拟蔗汁的吸附过程速率主要为多分子层吸附和化学吸附控制,CaCO3@ZL具有良好的再生性能,可用于蔗汁中酚酸的去除。

    Abstract:

    Objective: This study aimed to explore the adsorption performance and mechanism of phenolic acids in simulated sugarcane juice by nano-calcium carbonate modified zeolite (CaCO3@ZL). Methods: Using zeolite as the supporting framework, a co-precipitation technique was utilized to create nano-calcium carbonate modified zeolite (CaCO3@ZL), which was then employed to simulate the adsorption of phenolic acids in sugarcane juice. Using X-ray diffraction (XRD) and infrared spectroscopy (FTIR), the zeolite's characteristics were examined both before and after alteration. The kinetic model fitting of CaCO3@ZL and static adsorption studies were also conducted. The properties of phenolic acids were studied during adsorption. Results: XRD and FTIR characterization results indicate that the modification process successfully prepared nano-calcium carbonate loaded on the surface of zeolite CaCO3@ZL. Comparing the adsorption test results of CaCO3@ZL to those of the unmodified ZL, the adsorption capacity of phenolic acids increased by 40.34%, with adsorption equilibrium at 600 minutes. The fitting results showed that the adsorption process followed the Freundlich isotherm adsorption model and quasi-second-order adsorption kinetics model. After 5 regenerations CaCO3@ZL still maintains 80.39% of the initial adsorption amount of phenolic acid. Conclusion: The adsorption process rate of CaCO3@ZL on simulated sugarcane juice is mainly controlled by multi-molecular layer adsorption and chemical adsorption. CaCO3@ZL has good regeneration performance and can be used for the removal of phenolic acids in sugarcane juice.

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柳富杰,黄释慧,潘莉莉.纳米碳酸钙表面改性沸石对模拟蔗汁中酚酸的吸附性能[J].食品与机械,2024,40(1):33-39.
LIU Fujie, HUANG Shihui, PAN Lili. Study on the adsorption properties of nano-calcium carbonate surface modified zeolite to phenolic acid in simulated cane juice[J]. Food & Machinery,2024,40(1):33-39.

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  • 收稿日期:2023-02-01
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  • 在线发布日期: 2024-01-30
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