不同涂布率再造烟叶的热解特性及动力学分析
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(1. 郑州轻工业大学材料与化学工程学院,河南 郑州 450001;2. 黑龙江烟草工业有限责任公司技术研发中心,黑龙江 哈尔滨 150001;3. 郑州轻工业大学食品与生物工程学院,河南 郑州 450001)

作者简介:

张果,女,郑州轻工业大学实验师,硕士。

通讯作者:

岳先领(1979—),男,黑龙江烟草工业有限责任公司工程师,硕士。E-mail:78649504@qq.com

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基金项目:

黑龙江烟草工业有限责任公司科技项目(编号:PURREQ202005210006);国家自然科学基金项目(编号:41807401)


Thermal pyrolysis characteristics and kinetics study of reconstituted tobacco with different coating rates
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(1. Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou, Henan 450001, China; 2. Technology Center of Heilongjiang Tobacco Industry Co., Ltd., Harbin, Heilongjiang 150001, China; 3. College of Food and Biological Engineering, Zhengzhou University of Light Industry, Zhengzhou, Henan 450001, China)

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    摘要:

    为研究不同涂布率再造烟叶的热解特性,采用热分析技术并结合Coats-Redfern法研究了不同涂布率再造烟叶的热解行为及主要失重阶段的动力学参数变化规律,进一步监测了再造烟叶热解过程中的气体成分释放。结果表明:① 随再造烟叶涂布率增加,样品中C质量分数逐渐升高,O质量分数呈降低趋势,微观组织结构差异不明显。② 再造烟叶的热失重过程可分为干燥脱水(阶段Ⅰ)、低沸点挥发分析出(阶段Ⅱ)、半纤维素分解(阶段Ⅲ)、纤维素及木质素分解(阶段Ⅳ)、炭化(阶段Ⅴ)5个阶段。涂布率由35%增加到50%时,挥发分起始析出温度Ti由220.2 ℃逐渐降低至196.0 ℃,终止析出温度呈升高趋势,阶段Ⅲ和阶段Ⅳ的最大失重速率呈减小趋势,综合热解指数ICP逐渐降低。③ 热解动力学分析显示,阶段Ⅳ的反应活化能E及指前因子A均显著高于阶段Ⅲ的;相同升温速率下,随涂布率增加阶段Ⅲ的活化能从133.08 kJ/mol 升高至160.10 kJ/mol,阶段Ⅳ热解阶段的活化能变化幅度较小。另外,阶段Ⅲ的ΔH随涂布率增加逐渐升高,涂布物提高了该阶段热解所需的能量。④ 在线红外分析表明热解过程中的气体释放主要是小分子气体(如H2O、CH4、CO2、CO等)和轻质焦油组分(如醛酮酸和酚类等),其中CO2气体释放量显著高于其他成分,其次是CO代表的醛酮酸类成分、CC代表的芳香烃类及水分等。

    Abstract:

    In order to investigate the pyrolysis characteristics of reconstituted tobacco with different coating rates, thermogravimetry technique combined with Coats-Redfern method was adopted to study the pyrolysis behavior and the variation of kinetic parameters of main weight loss stages. Furthermore, the pyrolysis gas release behavior was monitored by TG-FTIR technique. The results showed that: ① The content of C increased gradually and the content of O decreased with the increase of coating rate of reconstituted tobacco. While the change in the microstructure of reconstituted tobacco was not obvious. ② The thermogravimetric process of reconstituted tobacco can be divided into five stages: drying dehydration (Stage Ⅰ), the volatilization of component with low boiling point (Stage Ⅱ), hemicellulose decomposition (Stage Ⅲ), cellulose and lignin decomposition (Stage Ⅳ), carbonization (Stage Ⅴ). With the coating rate increased from 35% to 50%, the initial release temperature of volatiles Ti decreased gradually from 220.2 ℃ to 196.0 ℃, the final release temperature exhibited increase trend, and the maximum weight loss rate of stage Ⅲ and Ⅳ decreased. The comprehensive pyrolysis index (ICP) decreased from 2.55×10-4%/(min·℃2) to 1.51×10-4%/(min·℃2) gradually with the increasing of coating rate. The heating rate also had a significant effect on the pyrolysis characteristic parameters of the samples. ③ The results of pyrolysis kinetics analysis based on Coats-Redfern method showed that the activation energy and pre-exponential factor stage Ⅳ were significantly higher than that of stage Ⅲ. The activation energy of stage Ⅲ increased from 133.08 kJ/mol to 160.10 kJ/mol with the increase of coating rate when under the same heating rate, while the activation energy of stage Ⅳ changed little. There was a kinetic compensation effect between the pyrolysis kinetic parameter E and lnA of reconstituted tobacco sample at different heating rates. In addition, the enthalpy change of stage Ⅲ increases from 128.48 kJ/mol to 155.52 kJ/mol with the increase of coating rate, which indicated that the coating components increased the energy required for pyrolysis. ④ The on-line FTIR analysis showed that the gas release during pyrolysis is mainly composed of small molecule gas (such as H2O, CH4, CO2, CO, etc.) and light tar components (such as aldehyde, ketone, acids and phenols, etc.). Among them, the amount of CO2 is significantly higher than other components, followed by aldehyde, ketone, and acids that represented by CO, followed by the aromatic hydrocarbons and water.

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张果,岳先领,叶建斌,等.不同涂布率再造烟叶的热解特性及动力学分析[J].食品与机械,2021,37(5):39-46.
ZHANGGuo, YUEXianling, YEJianbin, et al. Thermal pyrolysis characteristics and kinetics study of reconstituted tobacco with different coating rates[J]. Food & Machinery,2021,37(5):39-46.

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  • 收稿日期:2021-01-20
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  • 在线发布日期: 2023-02-15
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