高压离子色谱法快速测定饮用水中溴酸盐和亚硝酸盐
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陈景周,女,广州检验检测认证集团有限公司助理工程师,硕士

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Quickly determination of bromate and nitrite in drinking water by high pressure ion chromatography
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    摘要:

    采用Dionex Integrion高压离子色谱仪和Ionpac AS19高容量分析柱,以自动发生装置在线产生KOH作淋洗液,通过抑制型电导检测器进行饮用水样品中溴酸盐和亚硝酸盐含量的测定。结果表明,目标物溴酸盐和亚硝酸盐在5 min内实现分离,其检出限分别为0.46,0.22 μg/L。溴酸盐和亚硝酸盐分别在0~100,0~50 μg/L 呈良好的线性关系,其加标回收率分别为98.6%~101.3%,100.1%~106.0%,相对标准偏差分别为1.26%~4.12%,1.69%~4.27%。该方法简便快速,灵敏准确、环保高效,适用于饮用水中痕量溴酸盐和亚硝酸盐的测定。

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    A method of high pressure ion chromatography (HPIC) for quickly determinating bromate and nitrite in drinking water was established. The contents of bromate and nitrite in the sample were determined by using Dionex Integrion high-pressure ion chromatograph, IonPac AS19 high-capacity analytical column and inhibition conductivity detector, with the eluent of KOH produced on-line by automatic generation device. The anions of bromate and nitrite could be separated by the method within 5 min with detection limits of 0.46 μg/L and 0.22 μg/L respectively. In the concentration range of 0~100 μg/L for bromate and 0~50 μg/L for nitrite, a good linear relationship was found. By adding standards to the water, the recovery of bromate and nitrite was 98.6%~101.3% and 100.1%~106.0%, respectively, and the relative standard deviation was 1.26%~4.12% and 1.69%~4.27%. This method was simple, rapid, sensitive, accurate, efficient and environmentally friendly which was suitable to determinate the trace of bromate and nitrite in drinking water.

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陈景周,李樑,黄少漫,等.高压离子色谱法快速测定饮用水中溴酸盐和亚硝酸盐[J].食品与机械,2020,(7):63-66.
CHEN Jing-zhou, LI Liang, HUANG Shao-man, et al. Quickly determination of bromate and nitrite in drinking water by high pressure ion chromatography[J]. Food & Machinery,2020,(7):63-66.

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  • 在线发布日期: 2023-02-17
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