电感耦合等离子体质谱测定食盐中的铅含量
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(湖北省食品质量安全监督检验研究院,湖北 武汉 430060)

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朱影(1983—),女,湖北省食品质量安全监督检验研究院工程师,硕士。E-mail:riqiu@foxmail.com

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湖北省食品质量安全监督检验研究院自主立项项目(编号:ZZLX2015006)


Determination of lead in table salt by using internal standard method and standard addition method of ICP-MS
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(Hubei Provincical Institute for Food Supervision and Test, Wuhan, Hubei 430060, China)

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    摘要:

    选用铑(103Rh)作为内标物质,采用电感耦合等离子体质谱内标法和标准加入法分别对浓度为4%,8%,12%,16%,20%的食盐样品溶液中铅的加标回收率进行测定。试验结果表明:采用内标法测定时,当食盐样品浓度从4%增加至20%时,内标回收率从54.8%降低至5.1%,各浓度梯度高、中、低加标浓度样品的加标回收率在90%~112%;采用标准加入法测定时各浓度食盐样品基体对应的内标回收率基本保持在100%左右,各浓度梯度高、中、低加标浓度样品的加标回收率在91%~114%;采用电感耦合等离子体质谱内标法和标准加入法能够快速、准确地测定不同浓度食盐样品中的铅含量,而且食盐样品基体浓度从4%增加到20%并未对方法的准确性造成影响。

    Abstract:

    Rhodium (103Rh) was used as internal standard substance, and the recovery rates of lead in samples with different salt concentration of 4%, 8%, 12%, 16% were determined by using internal standard correction method and standard addition method of Inductively Coupled Plasma Mass Spectrometry(ICP-MS). The experimental results show that: When determined by internal standard correction method, as the table salt sample’s concentration increased from 4% to 20%, the recovery rates of the internal standard reduced from 54.8% to 5.1%, and the recovery rates of lead in high, medium and low standard addition samples with different concentration gradients of table salt were between 90%~112%; When determined by standard addition method, the internal standard recovery rates of each matrix of different salt concentration remained about 100%, and the recovery rates of lead in high, medium and low standard addition samples with different concentration gradients of table salt were between 91%~114%; Both the two analytical methods can accurately determine the content of lead in different concentration of table salt samples, and the accuracy of the methods did not affect although the matrix of table salt’s concentration increased from 4% to 20%.

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引用本文

朱影,付文雯,姚晓帆.电感耦合等离子体质谱测定食盐中的铅含量[J].食品与机械,2017,33(5):91-94.
ZHUYing, FUWenwen, YAOXiaofan. Determination of lead in table salt by using internal standard method and standard addition method of ICP-MS[J]. Food & Machinery,2017,33(5):91-94.

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  • 在线发布日期: 2023-03-10
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