直链淀粉链长对蜡质玉米淀粉膜性质的影响
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(1. 江南大学食品科学与技术国家重点实验室,江苏 无锡 214122;2. 江南大学食品学院,江苏 无锡 214122;3. 江南大学食品安全与营养协同创新中心,江苏 无锡 214122)

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孟令儒,女,江南大学在读硕士研究生。

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国家自然科学基金(编号:31301505);江苏省自然科学基金(编号:BK20130140,BE2013311)


Effects of amylose chain length on film properties ofwaxy maize starch
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(1.The State Key Laboratory of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu 214122, China; 2. School of Food Science and Technology, Jiangnan University, Wuxi, Jiangsu 214122, China; 3. Synergetic Innovation Center of Food Safety and Nutrition, Jiangnan University, Wuxi, Jiangsu 214122, China)

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    摘要:

    研究制备3种不同链长直链淀粉,并将其分别以8%,15%,25%的比例与蜡质玉米淀粉混合,采用流延法在23 ℃,相对湿度为85%的条件下干燥成膜。研究发现短链的脱支蜡质玉米淀粉(DWMS)与蜡质玉米淀粉混合成膜不发生相分离,而中等链长的玉米直链淀粉(MAM)和长链马铃薯直链淀粉(PAM)与蜡质玉米淀粉混合成膜时发生相分离。添加直链淀粉均可促进蜡质玉米淀粉结晶:蜡质玉米淀粉膜呈现无定形,DWMS添加比例由0%增加到15%时,淀粉膜结晶度增大,但添加比例进一步增加至25%时,结晶度下降; MAM与PAM的添加比例由0%增加到25%时淀粉膜的结晶度增加。淀粉膜结晶度与拉伸强度显著正相关(r=0.771),与穿刺强度显著正相关(r=0.780),与透油率显著负相关(r=-0.730)。DWMS的加入不影响蜡质玉米淀粉膜透光性和溶解性。随着直链淀粉链长以及添加比例的增加,淀粉膜透光率和溶解度降低。

    Abstract:

    Three types of amylose with different chain length were prepared. And each of them was added to waxy maize starch in the proportion of 8%, 15%, 25%, respectively. The mixed gelatinized starch solution was cast on to a plastic plate and dried at 23 ℃ in relative humidity (RH) of 85% for 3 days. The short amylose, i.e. debranched waxy maize starch (DWMS), mixed well with waxy maize starchwithout phase separation. But phase separation was found in the medium chain, i.e maize amylose (MAM), and long chain amylose, ie potato amylose (PAM), added films. Adding amylose promote crystallization of waxy maize starch. Waxy maize starch film was amorphous. When DWMS proportionincreased from 0% to 15%, the crystallinity of the waxy maize starch based film is increased, but further increase of DWMS proportion resulted in decrease of crystallinity; and the film crystallinity increased along with increase the proportion of MAM and PAM from 0% to 25%.The crystallinity of starch film was positively correlated with TS (r=0.771) and PS (r=0.780), and negatively correlated with Poil (r=-0.730). Waxy maize starch films and DWMS containing films exhibited good light permeability and solubility, whereas the light permeability and solubility were decreased with increase of the amylose chain length and the proportion of medium and long chain amylose.

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孟令儒,叶小嘉,吴春森,等.直链淀粉链长对蜡质玉米淀粉膜性质的影响[J].食品与机械,2016,32(6):19-24,48.
MENGLingru, YEXiaojia, WUChunsen, et al. Effects of amylose chain length on film properties ofwaxy maize starch[J]. Food & Machinery,2016,32(6):19-24,48.

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  • 在线发布日期: 2023-03-09
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